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Issue 40, 2017
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Spin fluorescence silencing enables an efficient thermally driven self-reporting polymer release system

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Abstract

We pioneer a self-reporting profluorescent release system driven by the thermo-reversible dynamic covalent ligation of chromophores to a lateral polymer chain, whose fluorescence is silenced by unpaired spins of nitroxide moieties prior to release. The introduced technology platform holds significant potential for imaging substrate release events.

Graphical abstract: Spin fluorescence silencing enables an efficient thermally driven self-reporting polymer release system

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Publication details

The article was received on 24 Aug 2017, accepted on 04 Sep 2017 and first published on 05 Sep 2017


Article type: Communication
DOI: 10.1039/C7PY01437F
Citation: Polym. Chem., 2017,8, 6199-6203
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    Spin fluorescence silencing enables an efficient thermally driven self-reporting polymer release system

    H. Mutlu, C. W. Schmitt, N. Wedler-Jasinski, H. Woehlk, K. E. Fairfull-Smith, J. P. Blinco and C. Barner-Kowollik, Polym. Chem., 2017, 8, 6199
    DOI: 10.1039/C7PY01437F

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