Jump to main content
Jump to site search


A triptycene-based two-dimensional porous organic polymeric nanosheet

Author affiliations

Abstract

The greater structural versatility of two-dimensional polymeric nanosheets could be available through the development of a bottom-up polymerization strategy compared with top-down nanosheets (such as graphene and metal chalcogenides). However, rational synthesis by solution polymerization has been a long-standing challenge. Considering that Glaser coupling is catalyzed by cuprous (I) salts with the participation of oxygen, an air/liquid interfacial coupling reaction has been designed and used to prepare a two-dimensional porous triptycene-based polymeric nanosheet (2D-PTNS). This 2D-PTNS shows a high BET surface area, good gas adsorption ability and excellent selective adsorption of C2H6/CH4 at ambient temperature and pressure.

Graphical abstract: A triptycene-based two-dimensional porous organic polymeric nanosheet

Back to tab navigation

Supplementary files

Publication details

The article was received on 06 Jul 2017, accepted on 08 Aug 2017 and first published on 08 Aug 2017


Article type: Paper
DOI: 10.1039/C7PY01122A
Citation: Polym. Chem., 2017, Advance Article
  •   Request permissions

    A triptycene-based two-dimensional porous organic polymeric nanosheet

    J. Chen, T. Zhai, Y. Chen, S. Geng, C. Yu, J. Liu, L. Wang, B. Tan and C. Zhang, Polym. Chem., 2017, Advance Article , DOI: 10.1039/C7PY01122A

Search articles by author

Spotlight

Advertisements