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Issue 37, 2017
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A post-polymerization functionalization strategy for the synthesis of sulfonyl (trifluoromethanesulfonyl)imide functionalized (co)polymers

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Abstract

In this Communication, we report the synthesis of a series of potassium sulfonyl (trifluoromethanesulfonyl)imide (STFSI) derivatives, bearing at one extremity the STFSI group and at the other extremity either bromo, azido or amine groups. The resultant STFSI derivatives were subsequently used in the post-polymerization functionalization of (co)polymers to yield functionalized (co)polymers by exploiting the highly efficient coupling reactions, namely alkylation, amidation and alkyne–azide cycloaddition.

Graphical abstract: A post-polymerization functionalization strategy for the synthesis of sulfonyl (trifluoromethanesulfonyl)imide functionalized (co)polymers

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Publication details

The article was received on 30 Jun 2017, accepted on 17 Aug 2017 and first published on 29 Aug 2017


Article type: Communication
DOI: 10.1039/C7PY01098B
Citation: Polym. Chem., 2017,8, 5660-5665
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    A post-polymerization functionalization strategy for the synthesis of sulfonyl (trifluoromethanesulfonyl)imide functionalized (co)polymers

    H. T. Ho, A. Tintaru, M. Rollet, D. Gigmes and T. N. T. Phan, Polym. Chem., 2017, 8, 5660
    DOI: 10.1039/C7PY01098B

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