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Poly(acrylamide-homocysteine thiolactone) as a synthetic platform for the preparation of polymeric ionic liquids by post ring-opening-orthogonal modifications

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Abstract

Poly(Acrylamide-Homocysteine Thiolactone) (PAHT) obtained by RAFT polymerisation can be used as a starting material for the synthesis, through its post modification, of a variety of advanced polymeric materials with different morphologies and a significant structural diversity. The examples here presented illustrate the utility of this approach for the preparation of functionalised polymers containing Ionic Liquid-like units (IL-like). These Polymeric Ionic Liquids (PILs) can be designed and obtained with a careful control of their structural elements according to the needs for a specific application.

Graphical abstract: Poly(acrylamide-homocysteine thiolactone) as a synthetic platform for the preparation of polymeric ionic liquids by post ring-opening-orthogonal modifications

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Publication details

The article was received on 25 Jun 2017, accepted on 19 Jul 2017 and first published on 19 Jul 2017


Article type: Paper
DOI: 10.1039/C7PY01067B
Citation: Polym. Chem., 2017, Advance Article
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    Poly(acrylamide-homocysteine thiolactone) as a synthetic platform for the preparation of polymeric ionic liquids by post ring-opening-orthogonal modifications

    S. Montolio, O. Zagorodko, R. Porcar, M. Isabel Burguete, S. V. Luis, H. Tenhu and E. García-Verdugo, Polym. Chem., 2017, Advance Article , DOI: 10.1039/C7PY01067B

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