Borazine-based inorganic–organic hybrid cyclomatrix microspheres by silicon/boron exchange precipitation polycondensation

Nicolas A. Riensch; Ayse Deniz; Sebastian Kühl; Lars Müller; Alina Adams; Andrij Pich; Holger Helten

doi:10.1039/C7PY01006K

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Borazine-based inorganic–organic hybrid cyclomatrix microspheres by silicon/boron exchange precipitation polycondensation†

Nicolas A. Riensch,^a Ayse Deniz,^b Sebastian Kühl,^b Lars Müller,^a Alina Adams,^c Andrij Pich

*^b and Holger Helten

*^a

Author affiliations

* Corresponding authors

^a Institute of Inorganic Chemistry, RWTH Aachen University, Landoltweg 1, 52056 Aachen, Germany
E-mail: holger.helten@ac.rwth-aachen.de

^b DWI – Leibniz Institute for Interactive Materials, Forckenbeckstraße 50, 52056 Aachen, Germany
E-mail: pich@dwi.rwth-aachen.de

^c Institute of Technical and Macromolecular Chemistry, RWTH Aachen University, Worringerweg 2, 52056 Aachen, Germany

Abstract

The synthesis of borazine-based hybrid cyclomatrix polymers has been studied under various conditions. Crosslinked polymers obtained via a novel silicon/boron exchange precipitation polycondensation approach form hybrid cyclomatrix microspheres with a mean diameter of about 900 nm.

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DOI: https://doi.org/10.1039/C7PY01006K
Article type: Communication
Submitted: 16 Jun 2017
Accepted: 14 Jul 2017
First published: 14 Jul 2017

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Polym. Chem., 2017,8, 5264-5268

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Borazine-based inorganic–organic hybrid cyclomatrix microspheres by silicon/boron exchange precipitation polycondensation

N. A. Riensch, A. Deniz, S. Kühl, L. Müller, A. Adams, A. Pich and H. Helten, Polym. Chem., 2017, 8, 5264 DOI: 10.1039/C7PY01006K

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Polymer Chemistry

Borazine-based inorganic–organic hybrid cyclomatrix microspheres by silicon/boron exchange precipitation polycondensation†

Abstract

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Borazine-based inorganic–organic hybrid cyclomatrix microspheres by silicon/boron exchange precipitation polycondensation

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