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Issue 36, 2017
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Versatile asymmetric thiophene/benzothiophene flanked diketopyrrolopyrrole polymers with ambipolar properties for OFETs and OSCs

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Abstract

Three novel asymmetric thiophene/benzothiophene-flanked diketopyrrolopyrrole (DPP)-based polymers with different π bridges, designated as PBTTDPP-BT, PBTTDPP-TT and PBTTDPP-2FBT, were designed, synthesized and employed in organic solar cells. Compared with the reported thiophene/pyridine-flanked DPP, these thiophene/benzothiophene-flanked DPP polymers exhibited narrower band gaps below 1.5 eV, leading to a broadened absorption that ranged from 500 nm to 850 nm. All polymers displayed promising ambipolar semiconducting properties. PBTTDPP-BT, PBTTDPP-TT and PBTTDPP-2FBT showed hole mobilities of 1.20, 1.68 and 1.50 cm2 V−1 s−1, respectively. Their corresponding electron mobilities were 0.40, 0.14 and 0.35 cm2 V−1 s−1. Interestingly, PBTTDPP-TT and PBTTDPP-2FBT also showed ambipolar properties in organic solar cells. Photovoltaic device based on PBTTDPP-TT as a donor material reached a power conversion efficiency (PCE) of 6.96% with PC71BM as an acceptor, while this device as the acceptor material achieved only 0.28% with poly(3-hexylthiophene) (P3HT) as the donor. In contrast, PCE of PBTTDPP-2FBT-based devices reached 5.62% with PC71BM and 0.44% with P3HT. These results suggest that the adoption of asymmetric flankers in DPP polymers can effectively tune their ambipolar transporting properties for high-performance organic electronic devices.

Graphical abstract: Versatile asymmetric thiophene/benzothiophene flanked diketopyrrolopyrrole polymers with ambipolar properties for OFETs and OSCs

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Publication details

The article was received on 07 Jun 2017, accepted on 08 Aug 2017 and first published on 08 Aug 2017


Article type: Paper
DOI: 10.1039/C7PY00940B
Citation: Polym. Chem., 2017,8, 5603-5610
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    Versatile asymmetric thiophene/benzothiophene flanked diketopyrrolopyrrole polymers with ambipolar properties for OFETs and OSCs

    Z. Jiang, Z. Ni, H. Wang, Z. Wang, J. Zhang, G. Qiu, J. Fang, Y. Zhang, H. Dong, K. Lu, W. Hu and Z. Wei, Polym. Chem., 2017, 8, 5603
    DOI: 10.1039/C7PY00940B

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