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A three-dimensional porphyrin-based porous organic polymer with excellent biomimetic catalytic performance

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Abstract

A highly stable porphyrin-based porous organic polymer PPOP-1(Fe) with a three-dimensional diamond structure was synthesized via imine condensation of a tetrahedral aldehyde and a linear porphyrin diamine. PPOP-1(Fe) exhibits excellent catalytic activity as a biomimetic catalyst, because the heme-like porphyrin active centers in PPOP-1(Fe) are exposed toward the open channels, thus accelerating the catalytic oxidation reactions.

Graphical abstract: A three-dimensional porphyrin-based porous organic polymer with excellent biomimetic catalytic performance

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Publication details

The article was received on 26 May 2017, accepted on 05 Jul 2017 and first published on 05 Jul 2017


Article type: Communication
DOI: 10.1039/C7PY00876G
Citation: Polym. Chem., 2017, Advance Article
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    A three-dimensional porphyrin-based porous organic polymer with excellent biomimetic catalytic performance

    W. Zhu, Z. Ding, X. Wang, T. Li, R. Shen, Y. Li, Z. Li, X. Ren and Z. Gu, Polym. Chem., 2017, Advance Article , DOI: 10.1039/C7PY00876G

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