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Issue 24, 2017
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Fe-Porphyrin functionalized microporous organic nanotube networks and their application for the catalytic olefination of aldehydes and carbene insertion into N–H bonds

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Abstract

Novel meso-tetraphenylporphyrin iron(III) chloride (Fe(TPP)Cl) functionalized microporous organic nanotube networks (Fe(TPP)Cl-MONNs) were successfully synthesized by an in situ hyper-crosslinking reaction between core–shell bottlebrush copolymers and Fe(TPP)Cl. The obtained Fe(TPP)Cl-MONN catalyst possesses a hierarchical porous structure, large surface area and good stability, which exhibits high catalytic activity and excellent reusability in the olefination of aldehydes and carbene insertion into N–H bonds with ethyl diazoacetate.

Graphical abstract: Fe-Porphyrin functionalized microporous organic nanotube networks and their application for the catalytic olefination of aldehydes and carbene insertion into N–H bonds

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Publication details

The article was received on 30 Mar 2017, accepted on 30 May 2017 and first published on 31 May 2017


Article type: Paper
DOI: 10.1039/C7PY00530J
Citation: Polym. Chem., 2017,8, 3721-3730
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    Fe-Porphyrin functionalized microporous organic nanotube networks and their application for the catalytic olefination of aldehydes and carbene insertion into N–H bonds

    M. Zhou, H. Zhang, L. Xiong, Z. He, T. Wang, Y. Xu and K. Huang, Polym. Chem., 2017, 8, 3721
    DOI: 10.1039/C7PY00530J

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