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Sequence-coded ATRP macroinitiators

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Abstract

Sequence-coded oligourethanes were tested as macroinitiators for the atom transfer radical polymerization (ATRP) of styrene. These oligomers were synthesized by solid-phase orthogonal iterative chemistry and transformed into ATRP initiators using a three-step modification procedure. A controlled radical polymerization behavior was observed with these macroinitiators, thus opening interesting opportunies for the synthesis of macromolecular architectures containing sequence-defined segments.

Graphical abstract: Sequence-coded ATRP macroinitiators

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Publication details

The article was received on 23 Mar 2017, accepted on 07 Apr 2017 and first published on 07 Apr 2017


Article type: Communication
DOI: 10.1039/C7PY00496F
Citation: Polym. Chem., 2017, Advance Article
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    Sequence-coded ATRP macroinitiators

    S. Telitel, B. É. Petit, S. Poyer, L. Charles and J. Lutz, Polym. Chem., 2017, Advance Article , DOI: 10.1039/C7PY00496F

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