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Synthesis of Photoresponsive Main-Chain Oligomers with Azobenzene Moieties via ADMET Oligomerization and their Micellization Properties

Abstract

We report the synthesis of azobenzene functionalized linear unsaturated/saturated polyolefine-oligomers. Using mild reaction conditions and different ruthenium-based catalysts, the azobenzene moieties are presisely placed in olefin chains via acyclic diene metathesis (ADMET) reaction (Mn,SEC = 3.0 kDa-8.0 kDa). Subsequent hydrogenation reactions with p-toluenesulfonhydrazide yields the fully saturated azobenzene oligomers, which are thoroughly chaacterized by 1H-NMR, FTIR and liquid chromatography under critical conditions (LCCC). The obtained saturated and unsaturated azobenzene oligomers are proven to form micelles in solution, where their sizes and morphologies are characterized by DLS and TEM. As a result of photo-isomerisation from the trans to cis state, the aggregates reduce in size, which is accompanied by a visible change of the solution from turbid to clear.

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Publication details

The article was received on 13 Mar 2017, accepted on 07 Apr 2017 and first published on 10 Apr 2017


Article type: Paper
DOI: 10.1039/C7PY00426E
Citation: Polym. Chem., 2017, Accepted Manuscript
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    Synthesis of Photoresponsive Main-Chain Oligomers with Azobenzene Moieties via ADMET Oligomerization and their Micellization Properties

    C. Appiah, G. Woltersdorf and W. H. Binder, Polym. Chem., 2017, Accepted Manuscript , DOI: 10.1039/C7PY00426E

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