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Issue 18, 2017
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Mechanistic studies of the copolymerization between ethyl diazoacetate and cinnamaldehyde

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Abstract

The Ndiazo,C3-diradical of diazomethane (˙N[double bond, length as m-dash]N–H2C˙) is a resonance structure with 1,3-dipole form. And alkyl diazoacetate (ethyl diazoacetate, EDA) can interact with α,β-unsaturated aldehyde (cinnamaldehyde, CA) without any catalyst to compose the Ndiazo,C5- and Ndiazo,C8-diradicals, which are the building species to produce the copolymer of EDA with CA through a sequential series of Ndiazo,Cω-diradical intermediates.

Graphical abstract: Mechanistic studies of the copolymerization between ethyl diazoacetate and cinnamaldehyde

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Publication details

The article was received on 09 Dec 2016, accepted on 02 Apr 2017 and first published on 03 Apr 2017


Article type: Paper
DOI: 10.1039/C6PY02126C
Citation: Polym. Chem., 2017,8, 2881-2888
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    Mechanistic studies of the copolymerization between ethyl diazoacetate and cinnamaldehyde

    Y. Li, C. Chen, F. Li, L. Liao and L. Liu, Polym. Chem., 2017, 8, 2881
    DOI: 10.1039/C6PY02126C

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