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Issue 6, 2017
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Synthesis of polymeric microcapsules by interfacial-suspension cationic photopolymerisation of divinyl ether monomer in aqueous suspension

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Abstract

Polymeric microcapusles have been synthesised with a markedly more hydrophillic monomer than previously reported, triethylene glycol divinyl ether, using cationic photopolymerisation in an aqueous environment. Characterisation by NMR and SEM show that the particles are formed with low dispersity with a size of approximately 1 μm in spite of the expected inhibition in aqueous conditions. Furthermore, supercritical carbon dioxide has been used to generate silver nanoparticles which distribute throughout the shell of the microcapsules further illustrating the structure of these capsules with characterisation by TEM and SAXS.

Graphical abstract: Synthesis of polymeric microcapsules by interfacial-suspension cationic photopolymerisation of divinyl ether monomer in aqueous suspension

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Publication details

The article was received on 12 Oct 2016, accepted on 05 Jan 2017 and first published on 06 Jan 2017


Article type: Communication
DOI: 10.1039/C6PY01782G
Citation: Polym. Chem., 2017,8, 972-975
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    Synthesis of polymeric microcapsules by interfacial-suspension cationic photopolymerisation of divinyl ether monomer in aqueous suspension

    M. Benedetti, T. R. Congdon, S. P. Bassett, M. Alauhdin, S. M. Howdle, D. M. Haddleton, R. Pisano, M. Sangermano and T. L. Schiller, Polym. Chem., 2017, 8, 972
    DOI: 10.1039/C6PY01782G

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