Photochemical synthesis of benzo[f]chromene

Abstract

The one-pot photocatalytic synthesis of benzo[f]chromene was performed at room temperature by the addition of benzyl alcohol, malononitrile and β-naphthol in contact with an illuminated nano-SnO₂/TiO₂ composite. This study illustrated the potential of photochemical synthesis of benzo[f]chromene. A simple procedure was proposed for the synthesis of a nano-SnO₂/TiO₂ composite using the sol–gel method by hydrolysis of tin(IV) chloride and titanium(IV) chloride at room temperature in the presence of polyethylene glycol 200, diethanolamine, and distilled water. Scanning electron microscopy (SEM), X-ray diffraction (XRD), and FT-IR were employed to characterize the proposed photocatalyst.