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New insight into efficient visible-light-driven photocatalytic organic transformation over CdS/TiO2 photocatalysts

Abstract

Selective transformation of organics by visible-light-driven photocatalysis was considered as a green and efficient strategy for synthesis of fine chemical. Herein, we fabricated the mesoporous structure TiO2 with CdS nanoparticles successfully by a photodeposition method. The photocatalytic selective oxidation of benzyl alcohols and reduction of 4-nitroaniline were demonstrated over the as-prepared samples under visible light irradiation, respectively. The CdS decorated TiO2 with photodeposition time of 90 min exhibited the highest activity, which was higher than that of the commercial CdS, bare TiO2, CdS/P25 and CdS/SiO2.Further experimental results indicated that the higher performance was attributed to the moderate deposition of CdS forming a closely connected heterjunction with TiO2, which promoted the separation of photogenerated electrons and holes. Based on the results of active species detection, the possible mechanism for photocatalytic selective oxidation of benzyl alcohol and reduction of 4-nitroaniline were proposed. Our study may provide guidance for selective transformation of organics by constructing heterojunction photocatalysts.

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Publication details

The article was received on 05 Jul 2017, accepted on 10 Nov 2017 and first published on 13 Nov 2017


Article type: Paper
DOI: 10.1039/C7PP00256D
Citation: Photochem. Photobiol. Sci., 2017, Accepted Manuscript
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    New insight into efficient visible-light-driven photocatalytic organic transformation over CdS/TiO2 photocatalysts

    Z. Hu, H. Quan, Z. Chen, Y. Shao and D. Li, Photochem. Photobiol. Sci., 2017, Accepted Manuscript , DOI: 10.1039/C7PP00256D

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