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Visible-light-promoted selective C–H amination of heteroarenes with heteroaromatic amines under metal-free conditions

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Abstract

The regioselective C–H amination of quinoline amides (C5) and imidazopyridines (C3) under transition-metal-free conditions at room temperature with a high degree of functional group tolerance is reported. The C–H amination promoted by visible light in the presence of a photocatalyst with a wide range of heteroamines makes the present protocol more sustainable.

Graphical abstract: Visible-light-promoted selective C–H amination of heteroarenes with heteroaromatic amines under metal-free conditions

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Publication details

The article was received on 10 Oct 2017, accepted on 27 Oct 2017 and first published on 27 Oct 2017


Article type: Communication
DOI: 10.1039/C7OB02504A
Citation: Org. Biomol. Chem., 2017, Advance Article
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    Visible-light-promoted selective C–H amination of heteroarenes with heteroaromatic amines under metal-free conditions

    S. Samanta, C. Ravi, S. N. Rao, A. Joshi and S. Adimurthy, Org. Biomol. Chem., 2017, Advance Article , DOI: 10.1039/C7OB02504A

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