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The synthesis of planar chiral pseudo-gem aminophosphine pre-ligands based on [2.2]paracyclophane

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Abstract

The synthesis of three planar chiral pseudo-gem disubstituted [2.2]paracyclophane-derived P,N-pre-ligands is reported along with preliminary results of their activity in the amination of aryl bromides and chlorides. The pseudo-gem aminophosphines were capable of mediating the coupling reaction at a loading of 1 mol%.

Graphical abstract: The synthesis of planar chiral pseudo-gem aminophosphine pre-ligands based on [2.2]paracyclophane

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Publication details

The article was received on 24 Sep 2017, accepted on 10 Oct 2017 and first published on 12 Oct 2017


Article type: Paper
DOI: 10.1039/C7OB02393F
Citation: Org. Biomol. Chem., 2017, Advance Article
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    The synthesis of planar chiral pseudo-gem aminophosphine pre-ligands based on [2.2]paracyclophane

    K. P. Jayasundera, T. G. W. Engels, D. J. Lun, M. N. Mungalpara, P. G. Plieger and G. J. Rowlands, Org. Biomol. Chem., 2017, Advance Article , DOI: 10.1039/C7OB02393F

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