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Issue 41, 2017
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I2/CHP mediated [1 + 1 + 1 + 1] cyclization of aromatic isocyanides with amines to construct 1,3-diazetidine-2,4-diimine derivatives

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Abstract

An I2/CHP (cumene hydroperoxide) mediated [1 + 1 + 1 + 1] cyclization of aromatic isocyanides with readily accessible amines via the formation 4 new C–N bonds has been developed to construct unsymmetric 1,3-diazetidine-2,4-diimine derivatives under mild conditions.

Graphical abstract: I2/CHP mediated [1 + 1 + 1 + 1] cyclization of aromatic isocyanides with amines to construct 1,3-diazetidine-2,4-diimine derivatives

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Publication details

The article was received on 08 Sep 2017, accepted on 30 Sep 2017 and first published on 03 Oct 2017


Article type: Paper
DOI: 10.1039/C7OB02255G
Citation: Org. Biomol. Chem., 2017,15, 8738-8742
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    I2/CHP mediated [1 + 1 + 1 + 1] cyclization of aromatic isocyanides with amines to construct 1,3-diazetidine-2,4-diimine derivatives

    H. Liu, T. Zhu, P. Xu, S. Wang and S. Ji, Org. Biomol. Chem., 2017, 15, 8738
    DOI: 10.1039/C7OB02255G

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