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Issue 40, 2017
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Controlling charge-transfer properties through a microwave-assisted mono- or bis-annulation of dialkynyl-N-(het)arylpyrroles

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Abstract

A selective microwave-assisted mono- and bis-annulation of dialkynyl-N-(het)arylpyrrole derivatives is described. These polycyclic aromatic hydrocarbons (PAHs) have been photophysically and computationally characterized. The mono-annulated systems display interesting charge-transfer properties. By contrast, these properties vanish within the more conjugated bis-annulated compounds.

Graphical abstract: Controlling charge-transfer properties through a microwave-assisted mono- or bis-annulation of dialkynyl-N-(het)arylpyrroles

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Publication details

The article was received on 28 Aug 2017, accepted on 26 Sep 2017 and first published on 26 Sep 2017


Article type: Paper
DOI: 10.1039/C7OB02149F
Citation: Org. Biomol. Chem., 2017,15, 8568-8575
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    Controlling charge-transfer properties through a microwave-assisted mono- or bis-annulation of dialkynyl-N-(het)arylpyrroles

    P. Pierrat, S. Hesse, C. Cebrián and P. C. Gros, Org. Biomol. Chem., 2017, 15, 8568
    DOI: 10.1039/C7OB02149F

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