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Issue 39, 2017
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Dynamic control over catalytic function using responsive bisthiourea catalysts

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Abstract

Two novel bisthiourea molecular motor-based catalysts were designed and their dynamic control of activity and stereoselectivity in the Henry reaction using heat and light as external stimuli was investigated. Enantioselective organocatalysis studies established that a basic functional group is not required within the catalyst core to effect efficient dual stereocontrol, illustrating novel stimuli responsive organocatalysts.

Graphical abstract: Dynamic control over catalytic function using responsive bisthiourea catalysts

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Publication details

The article was received on 26 Jul 2017, accepted on 22 Aug 2017 and first published on 31 Aug 2017


Article type: Paper
DOI: 10.1039/C7OB01851G
Citation: Org. Biomol. Chem., 2017,15, 8285-8294
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    Dynamic control over catalytic function using responsive bisthiourea catalysts

    M. Vlatković, J. Volarić, B. S. L. Collins, L. Bernardi and B. L. Feringa, Org. Biomol. Chem., 2017, 15, 8285
    DOI: 10.1039/C7OB01851G

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