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Issue 35, 2017
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BODIPY dyads from a,c-biladiene salts

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Abstract

Asymmetric dimers of BODIPY dyes were synthesized from a,c-biladiene salts in good yields; this work constitutes a new versatile approach to the synthesis of BODIPY dyads, which display red-shifted absorptions and emissions in the visible spectral region, higher fluorescence quantum yields and larger Stokes shifts compared with monomeric BODIPYs. The X-ray structure of a 5,5′-dibromo-BODIPY dyad was obtained, and the reactivity of this compound under Suzuki cross-coupling reaction conditions was investigated.

Graphical abstract: BODIPY dyads from a,c-biladiene salts

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Publication details

The article was received on 20 Jul 2017, accepted on 11 Aug 2017 and first published on 11 Aug 2017


Article type: Communication
DOI: 10.1039/C7OB01797A
Citation: Org. Biomol. Chem., 2017,15, 7255-7257
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    BODIPY dyads from a,c-biladiene salts

    A. Savoldelli, R. Paolesse, F. R. Fronczek, K. M. Smith and M. G. H. Vicente, Org. Biomol. Chem., 2017, 15, 7255
    DOI: 10.1039/C7OB01797A

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