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Issue 36, 2017
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Oxidative C–H functionalization of N-carbamoyl 1,2-dihydroquinolines

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Abstract

A modular and efficient method for the synthesis of α-substituted 1,2-dihydroquinolines is described. Under mild metal-free conditions, readily available N-carbamoyl 1,2-dihydroquinolines undergo oxidative C–H alkynylation, alkenylation, and allylation with a range of potassium trifluoroborates using TEMPO oxoammonium salt as an oxidant.

Graphical abstract: Oxidative C–H functionalization of N-carbamoyl 1,2-dihydroquinolines

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Publication details

The article was received on 20 Jul 2017, accepted on 25 Aug 2017 and first published on 25 Aug 2017


Article type: Paper
DOI: 10.1039/C7OB01793F
Citation: Org. Biomol. Chem., 2017,15, 7600-7606
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    Oxidative C–H functionalization of N-carbamoyl 1,2-dihydroquinolines

    Z. Liu, L. Chen, J. Li, K. Liu, J. Zhao, M. Xu, L. Feng, R. Wan, W. Li and L. Liu, Org. Biomol. Chem., 2017, 15, 7600
    DOI: 10.1039/C7OB01793F

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