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Issue 33, 2017
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Nickel-catalyzed N-vinylation of heteroaromatic amines via C–H bond activation

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Abstract

Here, we report a ligand- and reductant-free nickel-catalyzed N-vinylation of heteroaromatic amines using biorenewable p-cymene as a solvent. This unprecedented cross-coupling strategy has high functional group tolerance (halides, alkoxy, cyano, chiral motif, etc.) and proceeded via C–H bond activation.

Graphical abstract: Nickel-catalyzed N-vinylation of heteroaromatic amines via C–H bond activation

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Publication details

The article was received on 20 Jul 2017, accepted on 26 Jul 2017 and first published on 26 Jul 2017


Article type: Communication
DOI: 10.1039/C7OB01791J
Citation: Org. Biomol. Chem., 2017,15, 6896-6900
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    Nickel-catalyzed N-vinylation of heteroaromatic amines via C–H bond activation

    V. G. Landge, J. Rana, M. Subaramanian and E. Balaraman, Org. Biomol. Chem., 2017, 15, 6896
    DOI: 10.1039/C7OB01791J

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