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Issue 38, 2017
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Directed nucleophilic addition of phenoxides to cyclopropenes

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Abstract

The alkali metal-templated addition of aryloxides across the double bond of non-conjugated cyclopropenes is described. High cis-selectivity is achieved through a directing effect of a strategically positioned carboxamide functionality.

Graphical abstract: Directed nucleophilic addition of phenoxides to cyclopropenes

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Publication details

The article was received on 19 Jul 2017, accepted on 09 Sep 2017 and first published on 11 Sep 2017


Article type: Paper
DOI: 10.1039/C7OB01785E
Citation: Org. Biomol. Chem., 2017,15, 8153-8165
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    Directed nucleophilic addition of phenoxides to cyclopropenes

    P. Yamanushkin, M. Lu-Diaz, A. Edwards, N. A. Aksenov, M. Rubina and M. Rubin, Org. Biomol. Chem., 2017, 15, 8153
    DOI: 10.1039/C7OB01785E

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