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Intramolecular cyclopropylmethylation via non-classical carbocations

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Abstract

Cyclopropyl–cyclopropyl rearrangement can be achieved selectively by intramolecular trapping of cyclopropylmethyl carbenium ions with an internal nucleophile. This can be exploited as a useful method for the introduction of a cyclopropyl group into complex molecules using readily accessible disubstituted cyclopropane intermediates.

Graphical abstract: Intramolecular cyclopropylmethylation via non-classical carbocations

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Publication details

The article was received on 13 Jul 2017, accepted on 01 Aug 2017 and first published on 07 Aug 2017


Article type: Communication
DOI: 10.1039/C7OB01721A
Citation: Org. Biomol. Chem., 2017, Advance Article
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    Intramolecular cyclopropylmethylation via non-classical carbocations

    M. Skvorcova and A. Jirgensons, Org. Biomol. Chem., 2017, Advance Article , DOI: 10.1039/C7OB01721A

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