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Pd-Catalyzed double N-arylation of primary amines to synthesize phenoxazines and phenothiazines

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Abstract

An efficient and versatile Pd-catalyzed tandem C–N bond formation between aryl halides and primary amines is developed. The transformation allows a one-pot synthesis of phenoxazine and phenothiazine derivatives with a broad range of substitution patterns from readily available precursors.

Graphical abstract: Pd-Catalyzed double N-arylation of primary amines to synthesize phenoxazines and phenothiazines

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Publication details

The article was received on 25 Jun 2017, accepted on 07 Jul 2017 and first published on 07 Jul 2017


Article type: Communication
DOI: 10.1039/C7OB01540B
Citation: Org. Biomol. Chem., 2017, Advance Article
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    Pd-Catalyzed double N-arylation of primary amines to synthesize phenoxazines and phenothiazines

    L. Zhang, X. Huang, S. Zhen, J. Zhao, H. Li, B. Yuan and G. Yang, Org. Biomol. Chem., 2017, Advance Article , DOI: 10.1039/C7OB01540B

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