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Carpatizine, a novel bridged oxazine derivative generated by non-enzymatic reactions

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Abstract

Carpatizine (1), a new bridged oxazine derivative, was isolated from a marine-derived Streptomyces strain SNE-011. The structure was fully determined by spectroscopic analysis, ECD calculations and chemical methods. A plausible non-enzymatic reaction mechanism from daryamide D leading to carpatizine was presented, which was confirmed by chemical transformation.

Graphical abstract: Carpatizine, a novel bridged oxazine derivative generated by non-enzymatic reactions

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The article was received on 15 May 2017, accepted on 06 Jun 2017 and first published on 06 Jun 2017


Article type: Communication
DOI: 10.1039/C7OB01178D
Citation: Org. Biomol. Chem., 2017, Advance Article
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    Carpatizine, a novel bridged oxazine derivative generated by non-enzymatic reactions

    P. Fu and J. B. MacMillan, Org. Biomol. Chem., 2017, Advance Article , DOI: 10.1039/C7OB01178D

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