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Issue 27, 2017
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Palladium-catalyzed allylation of tautomerizable heterocycles with alkynes

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Abstract

A method for the allylic amidation of tautomerizable heterocycles was developed by a palladium catalyzed allylation reaction with 100% atom economy. A series of structurally diverse N-allylic substituted heterocycles can be synthesized in good yields with high chemo-, regio-, and stereoselectivities under mild conditions.

Graphical abstract: Palladium-catalyzed allylation of tautomerizable heterocycles with alkynes

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Publication details

The article was received on 07 May 2017, accepted on 19 Jun 2017 and first published on 19 Jun 2017


Article type: Paper
DOI: 10.1039/C7OB01119A
Citation: Org. Biomol. Chem., 2017,15, 5756-5763
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    Palladium-catalyzed allylation of tautomerizable heterocycles with alkynes

    C. Lu, D. Chen, H. Chen, H. Wang, H. Jin, X. Huang and J. Gao, Org. Biomol. Chem., 2017, 15, 5756
    DOI: 10.1039/C7OB01119A

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