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Reductive amination catalyzed by iridium complexes using carbon monoxide as a reducing agent

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Abstract

Development of novel, sustainable catalytic methodologies to provide access to amines represents a goal of fundamental importance. Herein we describe a systematic study for the construction of a variety of amines catalyzed by a well-defined homogeneous iridium complex using carbon monoxide as a reducing agent. The methodology was shown to be compatible with functional groups prone to reduction by hydrogen or complex hydrides.

Graphical abstract: Reductive amination catalyzed by iridium complexes using carbon monoxide as a reducing agent

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Publication details

The article was received on 25 Apr 2017, accepted on 11 Jul 2017 and first published on 11 Jul 2017


Article type: Paper
DOI: 10.1039/C7OB01005B
Citation: Org. Biomol. Chem., 2017, Advance Article
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    Reductive amination catalyzed by iridium complexes using carbon monoxide as a reducing agent

    A. P. Moskovets, D. L. Usanov, O. I. Afanasyev, V. A. Fastovskiy, A. P. Molotkov, K. M. Muratov, G. L. Denisov, S. S. Zlotskii, A. F. Smol'yakov, D. A. Loginov and D. Chusov, Org. Biomol. Chem., 2017, Advance Article , DOI: 10.1039/C7OB01005B

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