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Ag(I)-Catalyzed oxidative decarboxylation of difluoroacetates with activated alkenes to form difluorooxindoles

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Abstract

A silver-catalyzed oxidative decarboxylative gem-difluoromethylenation of difluoroacetates with activated alkenes under mild reaction conditions has been developed. This radical cascade reaction provides a new method for the construction of a variety of gem-difluoromethylenated oxindoles.

Graphical abstract: Ag(i)-Catalyzed oxidative decarboxylation of difluoroacetates with activated alkenes to form difluorooxindoles

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Publication details

The article was received on 19 Apr 2017, accepted on 30 May 2017 and first published on 31 May 2017


Article type: Paper
DOI: 10.1039/C7OB00955K
Citation: Org. Biomol. Chem., 2017, Advance Article
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    Ag(I)-Catalyzed oxidative decarboxylation of difluoroacetates with activated alkenes to form difluorooxindoles

    W. Wan, J. Li, G. Ma, Y. Chen, H. Jiang, H. Deng and J. Hao, Org. Biomol. Chem., 2017, Advance Article , DOI: 10.1039/C7OB00955K

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