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Organocatalytic synthesis of axially chiral atropisomers

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Abstract

This Review summarises the recent progress made in the organocatalytic synthesis of atropisomeric compounds. Methodologies based on dynamic kinetic resolution and direct access to BINOL-like biaryls are described. A particular emphasis is given to reaction mechanisms and to the development of strategies to obtain stable products by increasing the barrier to atropisomer interconversion during the reaction.

Graphical abstract: Organocatalytic synthesis of axially chiral atropisomers

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Publication details

The article was received on 12 Apr 2017, accepted on 03 May 2017 and first published on 03 May 2017


Article type: Review Article
DOI: 10.1039/C7OB00908A
Citation: Org. Biomol. Chem., 2017, Advance Article
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    Organocatalytic synthesis of axially chiral atropisomers

    P. Renzi, Org. Biomol. Chem., 2017, Advance Article , DOI: 10.1039/C7OB00908A

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