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Issue 20, 2017
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A room temperature cyanation of (hetero)aromatic chlorides by an air stable nickel(II) XantPhos precatalyst and Zn(CN)2

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Abstract

A methodology for the synthesis of (hetero)aromatic nitriles from aryl chlorides at room temperature has been developed. This methodology uses an air and moisture stable nickel(II) XantPhos precatalyst and Zn(CN)2 as the cyanide (CN) source.

Graphical abstract: A room temperature cyanation of (hetero)aromatic chlorides by an air stable nickel(ii) XantPhos precatalyst and Zn(CN)2

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Publication details

The article was received on 10 Apr 2017, accepted on 28 Apr 2017 and first published on 02 May 2017


Article type: Communication
DOI: 10.1039/C7OB00892A
Citation: Org. Biomol. Chem., 2017,15, 4291-4294
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    A room temperature cyanation of (hetero)aromatic chlorides by an air stable nickel(II) XantPhos precatalyst and Zn(CN)2

    D. D. Beattie, T. Schareina and M. Beller, Org. Biomol. Chem., 2017, 15, 4291
    DOI: 10.1039/C7OB00892A

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