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A cleft type receptor which combines an oxyanion hole with electrostatic interactions

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Abstract

A receptor for carboxylic acids which combines an oxyanion-hole structure with electrostatic forces has been prepared. X-ray diffraction studies have been carried out to evaluate the geometry of both the free receptor and its associated species with several carboxylic acids and many different arrangements have been discovered for the H-bond pattern in the associated species.

Graphical abstract: A cleft type receptor which combines an oxyanion hole with electrostatic interactions

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Publication details

The article was received on 20 Mar 2017, accepted on 03 May 2017 and first published on 03 May 2017


Article type: Paper
DOI: 10.1039/C7OB00679A
Citation: Org. Biomol. Chem., 2017, Advance Article
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    A cleft type receptor which combines an oxyanion hole with electrostatic interactions

    O. H. Rubio, S. D. Mazo, L. M. Monleón, L. Simón, Á. G. Temprano and J. R. Morán, Org. Biomol. Chem., 2017, Advance Article , DOI: 10.1039/C7OB00679A

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