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Triamide macrocyclic chloride receptors via a one-pot tandem reduction–condensation–cyclization reaction

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Abstract

A pyridine containing triamide macrocycle and its substituted analog have been synthesized in one pot from the corresponding monomer without the use of coupling reagents. The macrocycle can selectively bind chloride ions. The ease of synthesis and chloride-binding properties of the macrocycle make it a highly attractive scaffold for ion-encapsulation, ion-transport and water purification.

Graphical abstract: Triamide macrocyclic chloride receptors via a one-pot tandem reduction–condensation–cyclization reaction

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Publication details

The article was received on 16 Mar 2017, accepted on 02 May 2017 and first published on 02 May 2017


Article type: Communication
DOI: 10.1039/C7OB00642J
Citation: Org. Biomol. Chem., 2017, Advance Article
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    Triamide macrocyclic chloride receptors via a one-pot tandem reduction–condensation–cyclization reaction

    H. Behera, V. Ramkumar and N. Madhavan, Org. Biomol. Chem., 2017, Advance Article , DOI: 10.1039/C7OB00642J

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