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Issue 14, 2017
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Ruthenium-catalyzed regioselective allylic amination of 2,3,3-trifluoroallylic carbonates

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Abstract

We demonstrated the ruthenium-catalyzed allylic amination of 2,3,3-trifluoroallylic carbonates with several types of amines. The reactions proceeded with several types of amines, and succeeded in obtaining polyfluorinated terminal alkenes possessing branched allylic amines as a single regioisomer.

Graphical abstract: Ruthenium-catalyzed regioselective allylic amination of 2,3,3-trifluoroallylic carbonates

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Publication details

The article was received on 01 Mar 2017, accepted on 09 Mar 2017 and first published on 09 Mar 2017


Article type: Paper
DOI: 10.1039/C7OB00514H
Citation: Org. Biomol. Chem., 2017,15, 2938-2946
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    Ruthenium-catalyzed regioselective allylic amination of 2,3,3-trifluoroallylic carbonates

    S. Isobe, S. Terasaki, T. Hanakawa, S. Mizuno and M. Kawatsura, Org. Biomol. Chem., 2017, 15, 2938
    DOI: 10.1039/C7OB00514H

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