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Issue 13, 2017
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Stevens rearrangement of thioethers with arynes: a facile access to multi-substituted β-keto thioethers

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Abstract

An effective method for the synthesis of multi-substituted β-keto thioethers via Stevens rearrangement of simple β-keto thioethers with arynes has been developed. In these reactions, successive C–S/C–H/C–C bonds were formed in one pot under mild and transition-metal free conditions to afford multi-substituted β-keto thioethers in moderate to good yields.

Graphical abstract: Stevens rearrangement of thioethers with arynes: a facile access to multi-substituted β-keto thioethers

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Publication details

The article was received on 06 Feb 2017, accepted on 01 Mar 2017 and first published on 02 Mar 2017


Article type: Communication
DOI: 10.1039/C7OB00277G
Citation: Org. Biomol. Chem., 2017,15, 2716-2720
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    Stevens rearrangement of thioethers with arynes: a facile access to multi-substituted β-keto thioethers

    X. Xu, Z. Lin, Y. Liu, J. Guo and Y. He, Org. Biomol. Chem., 2017, 15, 2716
    DOI: 10.1039/C7OB00277G

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