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Issue 32, 2017
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Ultralight, highly thermally insulating and fire resistant aerogel by encapsulating cellulose nanofibers with two-dimensional MoS2

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Abstract

Thermally insulating materials, made from earth-abundant and sustainable resources, are highly desirable in the sustainable construction of energy efficient buildings. Cellulose from wood has long been recognized for these characteristics. However, cellulose can be a flammability hazard, and for construction this has been addressed via chemical treatment such as that with halogen and/or phosphorus, which leads to further environmental concerns. Fortunately, the structure of cellulose lends itself well to chemical modification, giving great potential to explore interaction with other compounds. Thus, in this study, cellulose nanofibers (CNFs) were nano-wrapped with ultrathin 1T phase molybdenum disulfide (MoS2) nanosheets via chemical crosslinking, to produce an aerogel. Thermal and combustion characterization revealed highly desirable properties (thermal conductivity k = 28.09 mW m−1 K−1, insulation R value = 5.2, limit oxygen index (LOI) = 34.7%, total heat release = 0.4 MJ m−2). Vertical burning tests also demonstrated excellent fire retardant and self-extinguishing capabilities. Raman spectra further revealed that MoS2 remained unscathed after 30 seconds of burning in a 1300 °C butane flame. Considering the inherently low density of this material, there is significant opportunity for its usage in a number of insulating applications demanding specific fire resistance properties.

Graphical abstract: Ultralight, highly thermally insulating and fire resistant aerogel by encapsulating cellulose nanofibers with two-dimensional MoS2

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Publication details

The article was received on 30 Mar 2017, accepted on 22 Jun 2017 and first published on 27 Jun 2017


Article type: Paper
DOI: 10.1039/C7NR02243C
Citation: Nanoscale, 2017,9, 11452-11462
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    Ultralight, highly thermally insulating and fire resistant aerogel by encapsulating cellulose nanofibers with two-dimensional MoS2

    L. Yang, A. Mukhopadhyay, Y. Jiao, Q. Yong, L. Chen, Y. Xing, J. Hamel and H. Zhu, Nanoscale, 2017, 9, 11452
    DOI: 10.1039/C7NR02243C

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