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Direct visualization of fluid dynamics in sub-10 nm nanochannels

Abstract

Optical microscopy is the most direct method to probe fluid dynamics at small scales. However, contrast between fluid phases vanishes at ~10-nm lengthscales, limiting direct optical interrogation to larger systems. Here, we present a method for direct, high-contrast and label-free visualization of fluid dynamics in sub-10 nm channels, and apply this method to study capillary filling dynamics at this scale. Direct visualization of confined fluid dynamics in 8-nm high channels is achieved with conventional bright-field optical microscope by inserting a layer of a high-refractive-index material, silicon nitride (Si3N4), between the substrate and the nanochannel, the height of which is accurately controlled down to a few nanometers by a SiO2 spacer layer. The Si3N4 layer exhibits a strong Fabry-Perot resonance in reflection, providing sharp contrast between ultrathin liquid and gas phases. In addition, the Si3N4 layer enables robust anodic bonding without nanochannel collapse. With this method, we demonstrate the validity of classical Lucas-Washburn equation for capillary filling in the sub-10 nm regime, in contrast to previous studies, for both polar and nonpolar liquids, and for aqueous salt solutions.

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Publication details

The article was received on 28 Mar 2017, accepted on 08 Jun 2017 and first published on 09 Jun 2017


Article type: Paper
DOI: 10.1039/C7NR02176C
Citation: Nanoscale, 2017, Accepted Manuscript
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    Direct visualization of fluid dynamics in sub-10 nm nanochannels

    H. Li, J. Zhong, Y. Pang, S. H. Zandavi, A. H. Persad, Y. Xu, F. Mostowfi and D. Sinton, Nanoscale, 2017, Accepted Manuscript , DOI: 10.1039/C7NR02176C

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