Jump to main content
Jump to site search


Interface interactions and enhanced room temperature ferromagnetism of Ag@CeO2 nanostructures

Author affiliations

Abstract

Enhancement of room temperature ferromagnetism (RTFM) has been achieved with core–shell metal–oxide nanoparticles (Ag@CeO2). To enhance the magnetic properties, interfacial charge transfer is achieved via the formation of a core–shell interface. Furthermore, by varying the shell thicknesses, additional control of the RTFM can be obtained. The Ag@CeO2 core–shell nanoparticles are synthesized successfully via a two-step method. Ag nanoparticles (NPs) are first synthesized on a TiO2 substrate by a thermally assisted photoreduction method, and then CeO2 NPs are deposited on the surface of Ag NPs by chemical reduction. No surfactants or organic compounds are used during the synthesis. At the interface between the core and the shell, electron transfers from the Ag-p orbital to the Ag-d and Ce-f orbitals are evidenced by X-ray absorption spectroscopy and electron energy loss spectroscopy. Such interfacial charge transfer results in enhanced room temperature ferromagnetism in the Ag@CeO2 core–shell NPs compared to the magnetism arising for bare Ag or CeO2 NPs. This study suggests that tailoring the interface, the surface and their coupling in nanostructured metal–oxide core shell nanoparticles is an effective way to enhance their magnetic properties.

Graphical abstract: Interface interactions and enhanced room temperature ferromagnetism of Ag@CeO2 nanostructures

Back to tab navigation

Supplementary files

Publication details

The article was received on 17 Mar 2017, accepted on 26 Jun 2017 and first published on 29 Jun 2017


Article type: Paper
DOI: 10.1039/C7NR01890H
Citation: Nanoscale, 2017, Advance Article
  •   Request permissions

    Interface interactions and enhanced room temperature ferromagnetism of Ag@CeO2 nanostructures

    S. Chen, E. Tseng, Y. Lai, W. Lee and A. Gloter, Nanoscale, 2017, Advance Article , DOI: 10.1039/C7NR01890H

Search articles by author

Spotlight

Advertisements