Jump to main content
Jump to site search

Issue 22, 2017
Previous Article Next Article

Phase transition and in situ construction of lateral heterostructure of 2D superconducting α/β Mo2C with sharp interface by electron beam irradiation

Author affiliations

Abstract

Lateral heterostructures of 2D materials have several interesting properties and potential applications, and they are usually fabricated by chemical vapor deposition. However, it still remains a great challenge to fabricate 2D lateral heterostructures with well-controlled patterns and sharp interfaces. Herein, we found that the 2D α-Mo2C crystal, a recently emerging 2D superconductor, experiences a phase transition from the α phase to β phase on electron beam irradiation in a transmission electron microscope because of the migration of carbon atoms among the molybdenum octahedrons. Combined with first-principles calculations, the carbon atom migration paths and the corresponding energy barriers were discussed. Utilizing this unique phase transition property of 2D α-Mo2C crystal, we demonstrated the precise in situ construction of the lateral heterostructure of 2D superconducting α/β Mo2C with a well-controlled pattern and sharp interface using advanced aberration-corrected scanning transmission electron microscopy.

Graphical abstract: Phase transition and in situ construction of lateral heterostructure of 2D superconducting α/β Mo2C with sharp interface by electron beam irradiation

Back to tab navigation

Supplementary files

Publication details

The article was received on 06 Mar 2017, accepted on 30 Apr 2017 and first published on 03 May 2017


Article type: Paper
DOI: 10.1039/C7NR01609C
Citation: Nanoscale, 2017,9, 7501-7507
  •   Request permissions

    Phase transition and in situ construction of lateral heterostructure of 2D superconducting α/β Mo2C with sharp interface by electron beam irradiation

    Z. Liu, Z. Fei, C. Xu, Y. Jiang, X. Ma, H. Cheng and W. Ren, Nanoscale, 2017, 9, 7501
    DOI: 10.1039/C7NR01609C

Search articles by author

Spotlight

Advertisements