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Phase transformation of TiO2 nanoparticles by femtosecond laser ablation in aqueous solution and deposited on conductive substrate

Abstract

Titanium dioxide (TiO2) is a wide bandgap semiconductor that is chemically stable, non-toxic, and economical compared to other semiconductors and has been implemented in a wide range of applications such as photocatalysis, photovoltaics, and memresistors. In this work we studied the femtosecond laser ablation of titanium dioxide powders (P25) dispersed either in water or deposited onto fluoride-doped tin oxide (FTO) substrate. The process was used as a route to induce the phase-transformation of TiO2 nanoparticles which results to be governed by the laser parameters such as ablation time and power. It was observed that upon increase of the ablation time of the TiO2 dispersion in water a bandgap widening occurred, leading to the possibility of bandgap engineering of TiO2 using controlled laser parameter profiles.

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Publication details

The article was received on 09 Jan 2017, accepted on 06 Apr 2017 and first published on 07 Apr 2017


Article type: Paper
DOI: 10.1039/C7NR00201G
Citation: Nanoscale, 2017, Accepted Manuscript
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    Phase transformation of TiO2 nanoparticles by femtosecond laser ablation in aqueous solution and deposited on conductive substrate

    P. Russo, R. Liang, R. X. He and Y. N. Zhou, Nanoscale, 2017, Accepted Manuscript , DOI: 10.1039/C7NR00201G

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