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Issue 22, 2017
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Water-stable [Ni(salen)]-type electrode material based on phenylazosubstituted salicylic aldehyde imine ligand

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Abstract

A novel electrode material was prepared by electrochemical oxidation of [4,4′-phenylazo-2,2′-(ethylenediimino-κ2N-methyl)diphenolate-κ2O]nickel, a [Ni(II)(salen)]-type complex, in chlorinated solvent. The chemical structure of the material was explored by FTIR, NMR and XPS techniques to determine the main components of the material and the nature of the linkage between them. The morphology of the material films was explored by SEM analysis. The electrochemical properties of the new material were studied by a set of voltammetric methods and an unusual stability of the material in aqueous medium was observed.

Graphical abstract: Water-stable [Ni(salen)]-type electrode material based on phenylazosubstituted salicylic aldehyde imine ligand

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Publication details

The article was received on 15 Sep 2017, accepted on 09 Oct 2017 and first published on 10 Oct 2017


Article type: Paper
DOI: 10.1039/C7NJ03526H
Citation: New J. Chem., 2017,41, 13918-13928
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    Water-stable [Ni(salen)]-type electrode material based on phenylazosubstituted salicylic aldehyde imine ligand

    A. A. Vereschagin, V. V. Sizov, P. S. Vlasov, E. V. Alekseeva, A. S. Konev and O. V. Levin, New J. Chem., 2017, 41, 13918
    DOI: 10.1039/C7NJ03526H

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