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Water-stable [Ni(salen)]-type electrode material based on phenylazosubstituted salicylic aldehyde imine ligand

Abstract

Novel electrode material has been obtained by electrochemical oxidation of [4,4'-phenylazo-2,2'-(ethylenediimino-κ2N-methyl)diphenolate-κ2O]nickel, a [Ni(II)(salen)]-type complex, in chlorinated solvent. The chemical structure of the material was explored by FTIR, NMR and XPS techniques to determine the main components of the material and the nature of linkage between them. The morphology of the material films was explored by SEM method. The electrochemical properties of the new material were studied by a set of voltammetric methods and unusual stability of the material in aqueous medium was found.

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Publication details

The article was received on 15 Sep 2017, accepted on 09 Oct 2017 and first published on 10 Oct 2017


Article type: Paper
DOI: 10.1039/C7NJ03526H
Citation: New J. Chem., 2017, Accepted Manuscript
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    Water-stable [Ni(salen)]-type electrode material based on phenylazosubstituted salicylic aldehyde imine ligand

    A. A. Vereshchagin, V. Sizov, P. Vlasov, E. V. Alekseeva, A. S. Konev and O. V. Levin, New J. Chem., 2017, Accepted Manuscript , DOI: 10.1039/C7NJ03526H

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