Issue 21, 2017
From the journal:

New Journal of Chemistry

A new procedure to obtain ε-caprolactam catalyzed by a guanidinium salt†

V. Fernández-Stefanuto,a   P. Verdía ORCID logo a  and  E. Tojo ORCID logo *a  

* Corresponding authors

a University of Vigo, Department of Organic Chemistry, Marcosende, 36210 Vigo (Pontevedra), Spain
E-mail: etojo@uvigo.es

Abstract

A new procedure to prepare ε-caprolactam by the Beckmann rearrangement of cyclohexanone oxime is described. Treatment of the oxime with the novel salt cyanoguanidinium tosylate affords ε-caprolactam without the need of any other promoter.

Graphical abstract: A new procedure to obtain ε-caprolactam catalyzed by a guanidinium salt

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Article information

DOI
https://doi.org/10.1039/C7NJ03443A
Article type
Paper
Submitted
11 Sep 2017
Accepted
26 Sep 2017
First published
04 Oct 2017

New J. Chem., 2017,41, 12830-12834

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A new procedure to obtain ε-caprolactam catalyzed by a guanidinium salt

V. Fernández-Stefanuto, P. Verdía and E. Tojo, New J. Chem., 2017, 41, 12830 DOI: 10.1039/C7NJ03443A

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