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A new procedure to obtain ε-caprolactam catalyzed by a guanidinium salt

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Abstract

A new procedure to prepare ε-caprolactam by the Beckmann rearrangement of cyclohexanone oxime is described. Treatment of the oxime with the novel salt cyanoguanidinium tosylate affords ε-caprolactam without the need of any other promoter.

Graphical abstract: A new procedure to obtain ε-caprolactam catalyzed by a guanidinium salt

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Publication details

The article was received on 11 Sep 2017, accepted on 26 Sep 2017 and first published on 04 Oct 2017


Article type: Paper
DOI: 10.1039/C7NJ03443A
Citation: New J. Chem., 2017, Advance Article
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    A new procedure to obtain ε-caprolactam catalyzed by a guanidinium salt

    V. Fernández-Stefanuto, P. Verdía and E. Tojo, New J. Chem., 2017, Advance Article , DOI: 10.1039/C7NJ03443A

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