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Ionic liquid/metal–organic framework hybrid generated by ion-exchange reaction: synthesis and unique catalytic activity

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Abstract

In this work, we succeeded for the first time in immobilizing an ionic liquid (IL) in a metal–organic framework (MOF) by using ion-exchange reactions. Interestingly, the resulting composites showed catalytic activities that were not observed with the original IL or the IL physically adsorbed on the MOF, implying that its ionic state was drastically changed upon immobilization.

Graphical abstract: Ionic liquid/metal–organic framework hybrid generated by ion-exchange reaction: synthesis and unique catalytic activity

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Publication details

The article was received on 30 Aug 2017, accepted on 16 Oct 2017 and first published on 16 Oct 2017


Article type: Paper
DOI: 10.1039/C7NJ03269B
Citation: New J. Chem., 2017, Advance Article
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    Ionic liquid/metal–organic framework hybrid generated by ion-exchange reaction: synthesis and unique catalytic activity

    Y. Takashima, M. Yokoyama, A. Horikoshi, Y. Sato, T. Tsuruoka and K. Akamatsu, New J. Chem., 2017, Advance Article , DOI: 10.1039/C7NJ03269B

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