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Issue 23, 2017
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A disc-like Co7 cluster with a solvent dependent catecholase activity

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Abstract

A new mixed valence antiferromagnetic Co7 disc characterized by spectral, crystallographic and magnetic studies exhibited a solvent dependent catecholase activity with Kcat(MeOH) = 2026 h−1. This report demonstrates the first example of a discrete heptanuclear disc showing solvent dependent catecholase activity.

Graphical abstract: A disc-like Co7 cluster with a solvent dependent catecholase activity

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Publication details

The article was received on 22 Aug 2017, accepted on 20 Oct 2017 and first published on 20 Oct 2017


Article type: Letter
DOI: 10.1039/C7NJ03149A
Citation: New J. Chem., 2017,41, 14057-14061
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    A disc-like Co7 cluster with a solvent dependent catecholase activity

    M. N. Ahamad, F. Sama, M. N. Akhtar, Y. Chen, M. Tong, M. Ahmad, M. Shahid, S. Hussain and K. Khan, New J. Chem., 2017, 41, 14057
    DOI: 10.1039/C7NJ03149A

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