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Facile fabrication of PS/Fe3O4@PANi nanocomposite particles and their application for effective removal of Cu2+

Abstract

This work presents a simple and straightforward approach to fabricating multifunctional nanocomposite particles which possess a core of polystyrene (PS) particle, transition layer of magnetic Fe3O4 nanoparticles (NPs), and an outer shell of adsorbable polyaniline (PANi). In detail, the positively charged Fe3O4 NPs synthesized by chemical co-precipitation method are directly loaded onto the negatively charged surface of PS particles obtained from emulsifier-free emulsion polymerization through electrostatic self-assembly; subsequently, the coating of resultant PS/Fe3O4 nanocomposite particles with PANi was successfully achieved by virtue of the “swelling–diffusion–interfacial-polymerization method” (SDIPM). Furthermore, the adsorption of Cu2+ by PS/Fe3O4@PANi nanocomposite particles was investigated by changing the initial pH value, adsorption time, and initial concentration of adsorbate. The adsorption data in our work follow a pseudo-second-order kinetics model and fit the Langmuir isotherm model. The PS/Fe3O4@PANi nanocomposite particles show the maximum adsorption capacity is up to 181.5 mg/g at the pH of 5. More importantly, these nanocomposite particles can be easily recovered using an external magnetic field owing to the presence of Fe3O4 NPs, and the regenerated nanocomposite particles can be repeatedly used for eight cycles without significant loss of their adsorption capacity.

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Publication details

The article was received on 22 Aug 2017, accepted on 10 Oct 2017 and first published on 11 Oct 2017


Article type: Paper
DOI: 10.1039/C7NJ03139D
Citation: New J. Chem., 2017, Accepted Manuscript
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    Facile fabrication of PS/Fe3O4@PANi nanocomposite particles and their application for effective removal of Cu2+

    Y. Li, J. Qiu, S. Ye, L. Wang, C. Yang, P. Sun and C. Wang, New J. Chem., 2017, Accepted Manuscript , DOI: 10.1039/C7NJ03139D

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