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Synthesis of polysubstituted 3,4-dihydro-2H-thiopyrans by regioselective annulation of 3,3-disubstituted allylic alcohols with a β-oxodithioester

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Abstract

Polyfunctionalized 3,4-dihydro-2H-thiopyrans were obtained in high yields via the regioselective annulation of 3,3-disubstituted allylic alcohols with a β-oxodithioester under BF3·Et2O catalysis.

Graphical abstract: Synthesis of polysubstituted 3,4-dihydro-2H-thiopyrans by regioselective annulation of 3,3-disubstituted allylic alcohols with a β-oxodithioester

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Publication details

The article was received on 14 Aug 2017, accepted on 06 Oct 2017 and first published on 09 Oct 2017


Article type: Letter
DOI: 10.1039/C7NJ03025H
Citation: New J. Chem., 2017, Advance Article
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    Synthesis of polysubstituted 3,4-dihydro-2H-thiopyrans by regioselective annulation of 3,3-disubstituted allylic alcohols with a β-oxodithioester

    S. Kurva, V. Sriramoju, S. Madabhushi and J. B. Nanubolu, New J. Chem., 2017, Advance Article , DOI: 10.1039/C7NJ03025H

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