Jump to main content
Jump to site search


Guest induced hysteretic tristability in 3D pillared Hofmann-type microporous metal–organic frameworks

Author affiliations

Abstract

Herein we report the synthesis, isolation and structural characterization of hybrid microporous Hofmann-like spin crossover polymers with the molecular formula {Fe(C4H4N2)[M(CN)4]}·(C4H4N2)·1.2H2O where M = Pt(II) (1), Pd(II) (2). Magnetic susceptibility studies showed well-resolved hysteretic three-step for 1 and two-step for 2 thermally induced spin transitions.

Graphical abstract: Guest induced hysteretic tristability in 3D pillared Hofmann-type microporous metal–organic frameworks

Back to tab navigation

Supplementary files

Publication details

The article was received on 04 Jul 2017, accepted on 25 Sep 2017 and first published on 26 Sep 2017


Article type: Letter
DOI: 10.1039/C7NJ02398G
Citation: New J. Chem., 2017, Advance Article
  •   Request permissions

    Guest induced hysteretic tristability in 3D pillared Hofmann-type microporous metal–organic frameworks

    C. D. Polyzou, N. Lalioti, V. Psycharis and V. Tangoulis, New J. Chem., 2017, Advance Article , DOI: 10.1039/C7NJ02398G

Search articles by author

Spotlight

Advertisements