Issue 21, 2017
From the journal:

New Journal of Chemistry

Guest induced hysteretic tristability in 3D pillared Hofmann-type microporous metal–organic frameworks†‡

C. D. Polyzou,a   N. Lalioti,a   V. Psycharisb  and  V. Tangoulis ORCID logo *a  

* Corresponding authors

a Department of Chemistry, Laboratory of Inorganic Chemistry, University of Patras, Patras, Greece
E-mail: vtango@upatras.gr

b Institute of Nanoscience and Nanotechnology, NCSR “Demokritos”, 15310 Ag. Paraskevi, Attikis, Greece

Abstract

Herein we report the synthesis, isolation and structural characterization of hybrid microporous Hofmann-like spin crossover polymers with the molecular formula {Fe(C4H4N2)[M(CN)4]}·(C4H4N2)·1.2H2O where M = Pt(II) (1), Pd(II) (2). Magnetic susceptibility studies showed well-resolved hysteretic three-step for 1 and two-step for 2 thermally induced spin transitions.

Graphical abstract: Guest induced hysteretic tristability in 3D pillared Hofmann-type microporous metal–organic frameworks

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Article information

DOI
https://doi.org/10.1039/C7NJ02398G
Article type
Letter
Submitted
04 Jul 2017
Accepted
25 Sep 2017
First published
26 Sep 2017

New J. Chem., 2017,41, 12384-12387

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Guest induced hysteretic tristability in 3D pillared Hofmann-type microporous metal–organic frameworks

C. D. Polyzou, N. Lalioti, V. Psycharis and V. Tangoulis, New J. Chem., 2017, 41, 12384 DOI: 10.1039/C7NJ02398G

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