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N-Confused porphyrins: complexation and 1H NMR studies

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Abstract

The complexation of 2-aza-21-carba-tetraphenylporphyrin and 2-aza-2-methyl-5,10,15,20-tetraphenyl-21-carbaporphyrin with nickel and zinc acetates in organic solvents has been investigated by UV-Vis spectroscopy and 1H NMR. It has been shown that the enhanced reactivity of these tetrapyrrolic macrocycles is mainly determined by their ability to exist in different tautomeric forms.

Graphical abstract: N-Confused porphyrins: complexation and 1H NMR studies

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Publication details

The article was received on 25 May 2017, accepted on 21 Jun 2017 and first published on 22 Jun 2017


Article type: Paper
DOI: 10.1039/C7NJ01814B
Citation: New J. Chem., 2017, Advance Article
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    N-Confused porphyrins: complexation and 1H NMR studies

    I. A. Khodov, O. V. Maltceva, V. V. Klochkov, O. I. Koifman and N. Zh. Mamardashvili, New J. Chem., 2017, Advance Article , DOI: 10.1039/C7NJ01814B

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