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Preparing Mn(III) salen-type Schiff base complexes using 1,3-oxazines obtained by Mannich condensation: towards removing ortho-hydroxyaldehydes

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Abstract

In this research a new method for preparing Mn(III)-salen complexes from 1,3-oxazine compounds has been investigated. The ligands were synthesized from the Mannich condensation of 1,2-diamines (1,2-ethylenediamine or 1,2-cyclohexanediamine) with phenolic compounds (2-naphthol or 4-flourophenol) and formaldehyde solution under reflux conditions. The reaction of the ligands with Mn(NO3)2·4H2O in methanol gave Mn(III) Schiff base complexes. The obtained compounds were characterized by elemental analysis and spectroscopic methods. The crystal structures of the ligand and complexes were characterized by single crystal X-ray diffraction studies. These analyses show that Mn(III)-salen type Schiff base complexes can be synthesized from the Mannich condensation of diamines, formaldehyde and phenols. This method eliminates the restrictions on the use of ortho-hydroxyaldehydes in preparing Mn(III)-Schiff base complexes.

Graphical abstract: Preparing Mn(iii) salen-type Schiff base complexes using 1,3-oxazines obtained by Mannich condensation: towards removing ortho-hydroxyaldehydes

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Publication details

The article was received on 08 May 2017, accepted on 27 Jul 2017 and first published on 28 Jul 2017


Article type: Paper
DOI: 10.1039/C7NJ01562C
Citation: New J. Chem., 2017, Advance Article
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    Preparing Mn(III) salen-type Schiff base complexes using 1,3-oxazines obtained by Mannich condensation: towards removing ortho-hydroxyaldehydes

    R. Bikas, M. Emami, K. Ślepokura and N. Noshiranzadeh, New J. Chem., 2017, Advance Article , DOI: 10.1039/C7NJ01562C

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